Crystal structure of chlorido(dimethyl sulfoxide-κS)bis[4-(pyridin-2-yl)benzaldehyde-κ3 C 2,N]iridium(III) acetonitrile monosolvate
نویسندگان
چکیده
The title compound, [IrCl(C12H8NO)2{(CH3)2SO}]·H3CCN or [IrCl(fppy)2(DMSO)]·H3CCN [where fppy is 4-(pyridin-2-yl)benzaldehyde and DMSO is dimethyl sulfoxide], is a mononuclear iridium(III) complex including two fppy ligands, a sulfur-coordinating DMSO ligand, and one terminal chloride ligand that define a distorted octa-hedral coordination sphere. The complex crystallizes from 1:1 DMSO-aceto-nitrile as an aceto-nitrile solvate. In the crystal, weak C-H⋯O and C-H⋯N hydrogen-bonding inter-actions between adjacent complexes and between the aceto-nitrile solvent and the complex consolidate the packing.
منابع مشابه
Crystal structure of cis,fac-{N,N-bis[(pyridin-2-yl)methyl]methylamine-κ3 N,N′,N′′}dichlorido(dimethyl sulfoxide-κS)ruthenium(II)
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